Abstract

The problem of copper leaching from copper-electrolyte slimes is discussed. To intensify the long and costly process, it is proposed to use a leaching system containing sulfuric acid and hydrogen peroxide as an oxidizing agent. The chemical transformations possible variants at the treatment of slime under the specified conditions and the thermodynamic parameters of the predicted reactions are considered. Solution composition effect on the copper dissolution rate at room temperature was studied in the presence of hydrogen peroxide using the rotating disc technique. It is found that dissolution rate constant at using hydrogen peroxide slightly inferior to dissolution rate constant under autoclaved conditions in an oxygen atmosphere.

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