Abstract

The method of moving reaction boundary (MRB) holds some significance for the colloid/or inorganic material synthesis, besides isoelectric focusing and capillary electrophoresis. However, theoretical studies have not been conducted for materials prepared by the moving reaction boundary method (MRBM). The concepts of product-concentration, product-rate and product-density of electro-migration reaction precipitate in MRBM were evolved. Some expressions were defined from the evolved concepts. The expressions were partially verified by some quantitative experiments of MRB with cobalt and hydroxyl ions in agarose gel. The theory developed here is of obvious significance for designing a new method preparing colloidal particles, for uniformly precipitating inorganic salts within gels, and for controlling the product-concentration, product-rate and product-density of electromigration reaction precipitate (viz. colloid/or inorganic material) in gels by MRBM.

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