Abstract
Ab initio SCF MO calculations are described for the radicals CH3, CCl3, CF3, SiH3, SiCl3, SiF3, PH+3, PCl+3 and PF+3. The calculated optimized geometries follow the prediction of Pauling using electronegativity arguments, and the calculated hyperfine coupling constants are in moderate agreement with the experimental values.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of the Chemical Society, Faraday Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.