Abstract
We have calculated the electronic states of Rb2 by multireference configuration interactions using the averaged relativistic effective small-core potential and the core-polarization potential. The potential energy curves for a large number of states dissociating into from 5s+5s up to 7s+5s asymptotic limits are calculated and the spectroscopic constants are reported. The spin–orbit effects for the states dissociating into 5p+5s and 4d+5s are calculated using the effective spin–orbit potential. The results are compared with available experimental data and other theoretical works.
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