Abstract

The microscopic mechanism of refractive indices, birefringence and spontaneous polarization of BaTiO3 and KNbO3 in the tetragonal phase is discussed by using a microscopic model. In this model, we have taken account of a quantum method based upon the orbital approximation and the dipole–dipole interaction due to the local field acting on the constituent ions. It is found that the electronic polarizabilities play a major role in these calculations and that the obtained results of the refractive indices, birefringence δn and spontaneous polarization are in good agreement with the experimental data.

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