Abstract
The microscopic mechanism of refractive indices, birefringence and spontaneous polarization of BaTiO3 and KNbO3 in the tetragonal phase is discussed by using a microscopic model. In this model, we have taken account of a quantum method based upon the orbital approximation and the dipole–dipole interaction due to the local field acting on the constituent ions. It is found that the electronic polarizabilities play a major role in these calculations and that the obtained results of the refractive indices, birefringence δn and spontaneous polarization are in good agreement with the experimental data.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.