Abstract

An extended two sublattice pseudospin lattice coupled mode model of Chaudhuri et al [Phys.Rev.338 (1988) 689] by adding third and fourth‐order phonon anharmonic interactions terms is considered for triglycine sulphate (CH2NH2COOH)3H2SO4 crystal and its isomorphs. With the help of double‐time temperature dependent Green's function method, expressions for shift,width, soft mode frequency, dielectric constant and loss tangent are derived. By fitting model values in the theoritical expressions, temperature dependence of soft mode frequency, dielectric constant and loss tangent are calculated. The theoretical results compare well with experimental results of Aravazhi et al [Ferroelectrics200 (1997) 279.]

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