Abstract
The structure of satellite (additional vacancies in N and/or O shells) and hypersatellite (additional vacancies in M or M and N shells) Mα1,2 and Mβ1 lines in the x-ray spectra of heavy atoms can be explained precisely by taking into account the extensive multiconfiguration Dirac–Fock calculations. The presented results are a precursor for the reliable quantitative interpretation of a very complex origin structure of Mα1,2 and Mβ1 lines in various high-resolution x-ray spectra of heavy atoms induced by different light and heavy projectiles. Moreover, the intensities of the M-x-ray lines of uranium can be helpful in the application of x-ray measurements from UO2 as a reference material (virtual standard) for non-destructive wavelength-dispersive electron probe microanalysis.
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