Abstract
The present paper describes a theoretical investigation of aqueous electrolytes in the infinite dilution limit. The linearized hypernetted chain theory is applied to solutions of hard spherical ions in a waterlike solvent at 25 °C and the properties of solution are studied as a function of ion size and charge. We examine both dynamical and equilibrium contributions to the apparent ‘‘dielectric constant’’ of solution and compare with previous theoretical calculations as well as with experimental measurements. Ion–solvent correlation functions and ion–ion potentials of mean force for several common electrolytes are also presented and discussed.
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