Abstract

The thermal shock resistance of ceramics depends on not only the mechanical and thermal properties of materials, but also the external constraint and thermal condition. So, in order to study the actual situation in its service process, a temperature-dependent thermal shock resistance model for ultra-high temperature ceramics considering the effects of the thermal environment and external constraint was established based on the existing theory. The present work mainly focused on the adjustment of the stress reduction factor according to different thermal shock situations. The influences of external constraint on both critical rupture temperature difference and the second thermal shock resistance parameter in either case of rapid heating or cooling conditions had been studied based on this model. The results show the necessity of adjustment of the stress reduction factor in different thermal shock situations and the limitations of the applicable range of the second thermal shock resistance parameter. Furthermore, the model was validated by the finite element method.

Highlights

  • Ultra-high temperature ceramics (UHTCs) are a family of ceramic-based composites mainly consisting of transition metal compounds, such as ZrB2, TaC, HfN and HfB2, which have melting points higher than 3,000 °C and can be potentially used at temperatures above 2,000 °C in an oxidizing environment

  • In the current experiment it is difficult to simulate the thermal environment and external constraint conditions suffered by the UHTCs, which were used as thermal protection materials

  • The Poisson ratio of the matrix base was equal to the UHTC plate, and the surface heat transfer coefficient was fixed in the calculation

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Summary

Introduction

Ultra-high temperature ceramics (UHTCs) are a family of ceramic-based composites mainly consisting of transition metal compounds, such as ZrB2, TaC, HfN and HfB2, which have melting points higher than 3,000 °C and can be potentially used at temperatures above 2,000 °C in an oxidizing environment. The research of TSR mostly focused on the effects of surface defects, temperature, indentation crack length [10,11], particle reinforced [12], whisker reinforced [13] or initial stress field [14] on TSR performance to explain the mechanisms of thermal shock failure. In the current experiment it is difficult to simulate the thermal environment and external constraint conditions suffered by the UHTCs, which were used as thermal protection materials. Due to the restrictions of current experiments, in the present investigation, a TSR model considering the effects of the thermal environment and external constraint had been established. The adjustment of stress reduction factor was considered and the influences of external constraint on both critical rupture temperature difference and the second TSR parameter in either case of rapid heating or cooling conditions had been studied. The present work was limited to establishing the TSR theoretical model and its validation by finite element simulation, which the experimental validation deferred to for future work

Derivation of the Theoretical Model
Heating Thermal Shock Conditions
Cooling Thermal Shock Conditions
Finite Element Model
Results and Discussion
Adjustment of Stress Reduction Factor
Limitations of the Applicable Range of the Second TSR Parameter
A Danger Region of Thermal Shock Initial Temperature
Conclusions
Full Text
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