Theoretical models from experiments on particle population in convective arrays

Abstract

Studying suspensions of gold nanorods has provided valuable knowledge on variations in concentration and how nanoparticles behave. Analysis of UV–visible spectra has shown changes in both longitudinal and transverse peaks, indicating a reduction in nanoparticle absorption peaks as the nanoparticle concentration decreases in suspension. Furthermore, changes in droplet contact angles have elucidated a direct correlation between nanoparticle density and droplet dynamics, shedding light on the intricate interplay between concentration reduction and droplet behavior. Investigations into cetyltrimethylammonium bromide (CTAB-coated) gold nanorods have unraveled the complexities of depletion, electrostatic, and Van der Waals forces, offering valuable knowledge on the self-assembly mechanisms governing these nanomaterials. The examination of interactions within coffee stain rings has underscored the crucial role of nanoparticle density in nanostructure arrangements, influencing deposition patterns and contributing to a deeper understanding of volume fraction evolution in nanostructured systems. By establishing a quantitative framework for interpreting energy parameters and observing optimal fitting agreements with experimental data, this research provides a solid foundation for future endeavors aimed at elucidating nanomaterial behavior in suspended systems. This comprehensive overview lays the groundwork for tailored manipulation of gold nanorod properties, emphasizing the essential relationship between density and contact angle in shaping wetting phenomena and surface engineering practices.