Abstract

We have solved the coupled momentum and continuity equations for NO +, O 2 +, and O +ions in the E- and F-regions of the ionosphere. This theoretical model has enabled us to examine the relative importance of various processes that affect molecular ion densities. We find that transport processes are not important during the day; the molecular ions are in chemical equilibrium at all altitudes. At night, however, both diffusion and vertical drifts induced by winds or electric fields are important in determining molecular ion densities below about 200 km. Molecular ion densities are insensitive to the O + density distribution and so are little affected by decay of the nocturnal F-region or by processes, such as a protonospheric flux, that retard this decay. The O + density profile, on the other hand, is insensitive to molecular ion densities, although the O + diffusion equation is formally coupled to molecular ion densities by the polarization electrostatic field. Nitric oxide plays an important role in determining the NO + to O 2 + ratio in the E-region, particularly at night. Nocturnal sources of ionization are required to maintain the E-region through the night. Vertical velocities induced by expansion and contraction of the neutral atmosphere are too small to affect ion densities at any altitude.

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