Abstract
We have earlier determined the dependence on the bending angle of the interaction of the methylene radical (CH2) in its X̃³B₁ state with He [L. Ma, P. J. Dagdigian, and M. H. Alexander, J. Chem. Phys. 136, 224306 (2012)]. By integration over products of the bending vibrational wave function, in a quantum close-coupled treatment we have calculated cross sections for the ro-vibrational relaxation of CH 2(X̃). Specifically, we find that cross sections for a loss of one vibrational quantum (v(b) = 2 → 1 and 1 → 0) are roughly two orders of magnitude smaller, and those for a loss of two vibrational quanta (v(b) = 2 → 0) four orders of magnitude smaller, than those for pure rotational relaxation. In addition, no clear cut dependence on the energy gap is seen.
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