Abstract
The purification of light hydrocarbons is one of the most important chemical processes globally which consumes substantial energy. Porous materials are likely to improve the efficiency of the separation process by acting as regenerable solid adsorbents. To investigate such translational systems, the underlying mechanism of adsorption in the porous materials must be taken into account. Herein we report the adsorption and selective separation of C1-C4 hydrocarbons in the coinage metal-based macrocyclic metallocavitand Pillarplex, which exhibits excellent performance in the adsorption of CH4 at the ambient conditions with a binding energy of -17.9 kcal mol-1. In addition, the endohedral adsorption of C2-C4 hydrocarbon is impressive. The CH4, C2H4, C3H4, and 1,3-butadiene have potential uptake of 2.57, 4.26, 3.60, and 2.95 mmol g-1, respectively at ambient conditions are highest from their respective isomers. Selective separation of C1-C4 hydrocarbons is studied using ideal adsorption solution theory demonstrating its potential for one-step purification of C1-C3 hydrocarbons.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.