Theoretical interpretation of the adsorption of amoxicillin on activated carbon via physical model.

Abstract

The paper describes a theoretical analysis of the adsorption of amoxicillin (AMX) onto two activated carbons pyrolysed at either 600 or 700 °C (PAC-600 and PAC-700). Series of experimental data are carried out at different temperatures ranging from 10 to 45 °C, as this is the first key factor to explain the adsorption mechanism of this pollutant. AMX adsorption capacity varied from 275 to 450 mg/g and between 276 and 454 mg/g for PAC-600 and PAC-700, respectively. It can be deduced that the pyrolysis temperature does not play a crucial role in AMX removal capacity of the adsorbents. A comparison with literature data shows that the retrieved adsorption capacities of both the adsorbents are very competitive for an effective water treatment. Physical models are applied to the two experimental data sets showing that a monolayer model with single energy is the best option to explain the AMX adsorption mechanism on both PAC-600 and PAC-700 adsorbents. The interpretation of the theoretical results points out that the AMX was not aggregated during the adsorption process. Under these experimental working conditions, it is noted that AMX is adsorbed almost via a parallel orientation on PAC-600 and PAC-700 adsorbents, reflecting that the adsorption is a multi-interaction mechanism. The model provides an estimation of the adsorption energy that allows the quantification of the interactions between the AMX and both PAC-600 and PAC-700 adsorbent surfaces; in both the cases, physical bindings are involved in AMX adsorption.