Abstract
By using the complete diagonalization method (CDM), the zero field splitting (ZFS) and g factors of the ground state ( A 2 4 ) and the first excited state ( E 2 ) for Mn 4+ ion in Al 2O 3 crystal are theoretically explained systematically. In our investigations, the spin–spin (SS), spin–other-orbit (SOO) and orbit–orbit (OO) interactions, which were omitted in most of the previous works, are taken into account. The calculated results show good agreement with the observed values. Also the contributions to the g factors of E 2 state from SS, SOO and OO interactions are discussed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
