Abstract
In this paper, based on the double-spin–orbit-coupling model, the third-order perturbation formulas of the crystal field (CF) mechanism and the charge-transfer (CT) mechanism, the spin-Hamiltonian parameters ([Formula: see text] factors: [Formula: see text], [Formula: see text], [Formula: see text] and hyperfine structure constants [Formula: see text]: [Formula: see text], [Formula: see text], [Formula: see text]) and the optical spectra of K2SO4:Mn[Formula: see text] crystal are theoretically explained. The contributions of the CF mechanism and the CT mechanism to the spin-Hamiltonian parameters are calculated and compared, and the results show that the contribution of the CT mechanism cannot be ignored when calculating the spin-Hamiltonian parameters of crystals doped with Mn[Formula: see text] ions. Meanwhile, the local structure of the impurity ions in the crystal is studied and the CF parameters of the crystal are acquired.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.