Abstract
Pillared clays are proposed as a new class of sorbents with properties similar to zeolites. However, despite extensive research, zeolites have not yet been replaced by pillared clays for industrial applications. In the present study a better understanding of the potential and limiting factors of Fe and mixed Fe-Zr pillared clays is focused by theoretical modelling calculations including interlayer distance, pillar symmetry, collapse and partial pillaring. The results are evaluated on microporosity and interpillar distance and are compared to experimental data.
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