Abstract

A coupled Hartree-Fock procedure has been employed to estimate the frequency shift in the infrared spectra of the S and R enantiomers of the CHFClBr molecule due to the parity-violating electroweak interaction. The calculations indicate that a resolving power $\ensuremath{\nu}/\ensuremath{\Delta}\ensuremath{\nu}\ensuremath{\approx}1\ifmmode\times\else\texttimes\fi{}{10}^{16},$ i.e., three orders of magnitude larger than that obtained in recent experiments, would be necessary to detect the parity-violating effects. The largest frequency shift was found for C-Cl stretching.

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