Abstract
The 'solution' analogues of four single-gas adsorption isotherms [i.e. the Langmuir–Freundlich (LF), the generalized Langmuir (GL), the Toth (T) and the LF–GL equations] were examined. The derived expressions were applied to the description of the experimental adsorption data relating to the sorption of a binary liquid solution containing components of unlimited miscibility on to microporous solids. Optimization of the equation parameters, as well as a comparison of the results obtained with those determined earlier for sorption in systems where the components were of limited miscibility, was undertaken.
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