Theoretical calculations on Landé g-factors and quadratic Zeeman shift coefficients of nsnp clock states in Mg and Cd optical lattice clocks

Abstract

The study of magnetic field effects on the clock transition of Mg and Cd optical lattice clocks is scarce. In this work, the hyperfine-induced Landé g-factors and quadratic Zeeman shift coefficients of the nsnp clock states for 111,113Cd and 25Mg were calculated by using the multi-configuration Dirac–Hartree–Fock theory. To obtain accurate values of these parameters, the impact of electron correlations and furthermore the Breit interaction and quantum electrodynamical effects on the Zeeman and hyperfine interaction matrix elements, and energy separations were investigated in detail. We also estimated the contributions from perturbing states to the Landé g-factors and quadratic Zeeman shift coefficients concerned so as to truncate the summation over the perturbing states without loss of accuracy. Our calculations provide important data for estimating the first- and second-order Zeeman shifts of the clock transition for the Cd and Mg optical lattice clocks.