Abstract
Two‐photon absorption (TPA) properties of several π‐conjugated molecules are theoretically investigated by ab initio molecular orbital method. The TPA properties of two typical classes of π‐conjugated molecules, which represent centrosymmetric and noncentrosymmetric systems, are investigated. In case of centrosymmetric (quadrupolar) molecules, the TPA intensity is found to be governed not only by the conventional parity selection rule but also by a symmetry property called alternancy symmetry, which is specific to the π‐conjugated systems. It is found that in order for such symmetric π‐conjugated molecules to have large TPA activity at the lower TPA allowed excited states, breaking of the alternancy symmetry is effective. In case of noncentrosymmetric (dipolar) molecules, the total TPA cross sections are separated into each contributing term such as the dipolar term or three‐state term. It is found that the dipolar term is predominant only for the lowest π‐π* state while for the higher excited states the three‐state terms become predominant. The effects of more structural factors such as intramolecular rotations on the TPA properties are discussed.
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