Abstract

AbstractThe gas phase reactions of metal ions (Al+, Cu+) with amine molecules [CH3NH2=MA, (CH3)2NH=DMA] were investigated using a laser ablation‐molecular beam method. The directly associated product complex ions,Al+‐MA and Al+‐DMA, and the dehydrogenation product ions, Cu+(CH2NH) and Cu+(C2H5N), as well as hydrated ion Cu+(NC2H5·H2O), have been obtained and recorded from the reactions of the metal ions and organic amine molecules, and density functional theory (B3LYP) calculations have been performed to reveal the optimized geometry, energetics, and reaction mechanism of the title reactions with basis set 6‐311+G(d,p) adopted.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.