Abstract
An attempt has been made to produce vanadium (III) oxychloride, (OVCl) by an on-line process for the first time using vanadium oxytrichloride, VOCl3 as a precursor passed over heated silver wool at about 930°C. The vapour products have been characterised by their infrared spectra; values for ν3 of 1010 cm−1 (O=V stretch) and for ν2 of 420 cm−1 (V-Cl stretch) were obtained. Ab initio self-consistent-field molecular orbital calculations were performed to determine the geometry, total energy and the vibrational frequencies of OVCl.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
