Theoretical and experimental analysis on effect of porous silicon surface treatment in multicrystalline silicon solar cells

Abstract

As widely known in silicon-based solar cells, the intrinsic parameters are decisive factors for internal quantum efficiency (IQE) and solar cells performances. Particularly, the front surface recombination velocity is one of the most important electrical parameters used to quantify the optoelectronic quality of the solar cells. In this study, the impact of the front surface recombination velocities (Sf) and anti-reflection coating are examined. Theoretical analysis shows that a decrease in Sf enhances the IQE for photons with shorter wavelengths (400–700nm). Cells with front porous silicon treatment (PS) was made and studied under ambient condition to improve performance of solar cells. In fact, internal quantum efficiency of mc-Si solar cells with PS was enhanced in shorter wavelengths, while the reflectivity was reduced to about 7% after PS treatment and conversion efficiency was improved by about 5% compared with conventional mc-Si solar cells. Furthermore, the laser-beam-induced current (LBIC) mapping shows that the PS treatment improves their quantum response.