Abstract
Equations of the polarographic current-potential curves are derived for electrode reactions of the type 2A+ze−ks,α→B coupled by an irreversible chemical regeneration reaction B+Ck→2A+D. Analytical solutions based on a general treatment were derived, including reversible, irreversible and quasi-reversible electrode processes. The kinetic domain over which an irreversible following chemical reaction affects the half-wave potentials is defined.
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