Abstract
Abstract (±)-2-Thiono-2-mercapto-α,α′-dinaphtho-(d,f)(1,3,2)-dioxophosphepin and a number of related compounds which contain a cyclic phosphoric ring all manifested clathrating properties. An X-ray examination of the p-xylene clathrate revealed that the main mode of action in this new class of clathrates is exclusively derived from the topological interaction of the host molecules, the alternating chirality of the binaphthyl unit plays a decisive role in the cavity making.
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