Abstract
Using 3- o-carborane derivatives as examples it has been shown that the Wolff, Beckmann, Hofmann, Curtius and Schmidt rearrangements proceed through BC bond cleavage and migration of the electron rich 3- o-carboranyl group to an electron deficient center. The Bayer-Villiger reaction of (1-methyl- o-carborane-3-yl)phenylketone results in migration of the 1-methyl 3- o-carboranyl group.
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