Abstract

In this study, the Ti-Al-Si + xTiC (x = 0, 2, 6, 10 wt.%) composite coatings, each with a different content of TiC were fabricated on a Ti-6Al-4V alloy by laser surface cladding. The microstructure of the prepared coatings was analyzed by the scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). The microhardness and the wear resistance of these coatings were also evaluated. The results show that α-Ti, Ti3Al, Ti5Si3, TiAl3, TiAl, Ti3AlC2 and TiC particles can be found in the composites. The microstructure can obviously be refined by increasing the content of TiC particles, while the microhardness increases and the coefficient of friction decreases. The Ti-Al-Si-6TiC composite shows the best wear resistance, owing to its relatively fine microstructure and high content of TiC particles. The microhardness of this coating is 5.3 times that of the substrate, while the wear rate is only 0.43 times. However, when the content of TiC was up to 10 wt.%, the original TiC could not be dissolved completely during the laser cladding process, leading to formation of cracks on the coatings.

Highlights

  • Titanium and its alloy have extensive usage in aerospace, chemical processing, power generation, marine, sports, medical and transportation industries by virtue of their low density, high specific strength, high creep resistance, high temperature mechanical properties, and superior corrosion resistance [1,2]. If these alloys are to be used in a wider application area, such as in load bearing contacts, wear resistance improvement is necessary

  • Surface modification techniques consist of two major aspects: one is processing technology, and the other is the design of coating material

  • The results showed that the hardness and wear resistance of Ti-Al-Si coating can be significantly improved compared to the Ti-6Al-4V substrate

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Summary

Introduction

Titanium and its alloy have extensive usage in aerospace, chemical processing, power generation, marine, sports, medical and transportation industries by virtue of their low density, high specific strength, high creep resistance, high temperature mechanical properties, and superior corrosion resistance [1,2]. In the coatings with TiC, the reinforcing phase TiC is scattered in the cladding layer oped awnidthhoabsvnioouosblvyCiodruaesncksgerradaniedntfidniesrtrcibryusttiaolns.cIhnarthacetehreiasttiacsff.eTchteedstzrouncetu, rtheeiscwoaetlilndgevaneldthe substrate are intertwined. This is because the two zones have the same structure, which are both needle-shaped α-Ti with good compatibility. The similar needle-shape structure is shown in Wu et al.’s work, where it is inferred that it is a saturated acicular structure of α-Ti solid solution containing Al, V, Si, and other elements of a [21] They can be closely fused with each other to fo1r0m0 μamgood metallurgical bonding, and it can be inferred that the coating and the substrate have a high bonding strength, which is ben-. Found that the microstructure of Ti-Fe was obviously refined with increasing the content of TiC particles

XRD and EDS Analysis of Coatings
Microhardness Analysis
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