Abstract

AbstractMonthly zonal mean observations of H2O and CH4 made by the limb infrared monitor of the stratosphere (LIMS) and the stratospheric and mesospheric sounder (SAMS) instruments on Nimbus 7 have been used to investigate whether the H2O mixing ratios in the stratosphere are consistent with a source via the oxidation of CH4. While both sets of data show considerable seasonally varying structure, total hydrogen (neglecting molecular hydrogen) is relatively featureless with a mean value over the stratosphere of 6.0±0.35 p.p.m.v. (1σ) for the five‐month period studied. The uniformity of the total hydrogen fields points to the validity of the CH4 oxidation hypothesis.The derived fields of total hydrogen are used to deduce a mean H2O mixing ratio for air as it enters the stratosphere of 2.7±0.35 p.p.m.v. (1σ) from which a desiccation temperature may be deduced (for example. −87.2°C at 60 mb).

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