Abstract
The i.r. and Raman spectra of solid tetrakistribromophosphinenickel(0), Ni(PBr 3) 4, are reported. The molecular symmetry is consistent with the requirements of the T d point group. A force constant calculation on the A 1 block of frequencies was carried out using an SVFF approximation neglecting the interaction force constants and a significant decrease in the force constant for ν(NiP) stretching compared to Ni(PF 3) 4 was observed.
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