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Abstract
Internal vibrational modes of the allyl groups in P(CH 2CHCH 2) 3 and As(CH 2CHCH 2) 3 may be assigned in terms of a local symmetry, C s , with non-interacting allyl units. The skeletal, E(CC) 3, modes require the assumption of an overall molecular symmetry of C 3, with all the allyl groups in the gauche-conformation.
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