Abstract
The infrared spectra of CH 3SH and CH 3SD have been investigated in the gas, liquid and solid state with the purpose of resolving some inconsistencies in the fundamental frequency assignment of CH 3SH. A study of the Raman spectra of liquid CH 3SH and CH 3SD to complement the infrared results was also carried out. A modified valence force field which included the diagonal symmetrized force constants plus a single added repulsive interaction constant coupling the methyl wagging with the SH bending vibrations was used in a normal coordinate treatment. Excellent agreement between the observed and calculated frequencies was obtained.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Spectrochimica Acta Part A: Molecular Spectroscopy
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
