Abstract
Abstract The infrared and Raman spectra of n-propyl mercaptan have been measured and vibrational assignments made with relation to the rotational isomerism. The normal vibration calculation has been carried out in a modified Urey-Bradley force field. In the gaseous and liquid states, TT and GT molecular forms have been confirmed to exist. An appreciable energy difference in the isomers has been found even in the liquid state. The TT form has a lower energy than the GT form. The CH2 hydrogen deformation frequencies of CH2CH2 groups in molecules similar to n-propyl mercatpan have been listed and discussed in relation to their molecular forms.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
