Abstract
The vapor phase Raman spectra of the molecules SPF 3, FCCl 3, and BrCCl 3 have been recorded at pressures of up to 1 atm over the fundamental frequency regions. The Raman band contours of the e-species fundamentals have been analyzed to yield first-order Coriolis coupling constants from which, together with the fundamental frequencies, e-species force constants of the general harmonic potential function have been evaluated. The results for thiophosphoryltrifluoride are compared with those deduced previously on the basis of infrared band contour analyses.
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