Abstract
The vapor heat capacities of acetone-chloroform, benzene-carbon tetrachloride and benzene-ethanol binary mixtures as a function of temperature and composition have been measured under atmospheric pressure in a multicomponent vapor flow calorimeter. It was found that the heat capacities of benzene-carbon tetrachloride vapors display ideal behavior, while those of acetone-chloroform vapors demonstrate positive deviation and those of benzene-ethanol vapors, negative deviation from the ideal linear additive values. These phenomena are explained and discussed.
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