The validity of the average t-matrix approximation for low-energy electron diffraction from random alloys

Abstract

We explore the validity of the average t-matrix approximation for the calculation of low-energy electron diffraction IV spectra from substitutionally disordered alloy surfaces. The accuracy of this approximation is assessed by comparison with the results of calculations for Ni x Pt 100− x (100) surfaces obtained using the more accurate coherent-potential approximation. We find excellent agreement the two approaches, demonstrating the validity of the average t-matrix approximation for interpreting low-energy electron diffraction from alloys. The physical origin of this agreement is discussed by reference to the scattering properties of the electrons in alloy surfaces.