Abstract
The valence of thallium ions in excess of the stoichiometric compositions of the liquid alloys Tl 2Te and Tl 2Se has been determined in past work by comparing the electrical properties with the results of doping with various third metals. We examine the pertinent equations and show that errors have occured in the original work on both of these systems. The thallium ions have a valence of one rather than three.
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