Abstract
The vacuum ultra-violet photoelectron spectrum of the SiO(X1Σ+) molecule has been recorded and interpreted with the aid of both ab initio molecular orbital and multiple-scattering Xα calculations. Three bands have been observed with vertical ionization potentials of 11·61, 12·19 and 14·80 eV, corresponding to ionization to the X2Σ+, A2Π and B2Σ+ states of SiO+ respectively. Estimates of r e, and D e for these ionic states have been made.
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