Abstract

Thermogravimetry was employed to study the changes occurring in rubber vulcanizates during devulcanization carried out by microwave treatment, a new promising method of recycling rubber waste. The thermogravimetric parameters Ti, T5 and Tp and the compositions of devulcanizates in comparison with vulcanizates were determined. The results obtained allowed estimation of the degree of destruction of the polymer chains in response to microwave treatment and permitted establishment of the most advantageous conditions of devulcanization in order to obtain the best properties of rubber devulcanizates for reuse in rubber processing. The results demonstrated that thermogravimetry is a very useful method for investigation and control of the microwave devulcanization process.

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