The Use of the Novel Optical Method SEZO AM (WiRan Ltd.) for Measurements of Particulate Matter (PM10–2.5) in Port Areas-Case Study for Port of Gdynia (Poland)

Abstract

From 1 March to 30 April and from 1 August to 30 September 2021, comparative studies of PM2.5 and PM10 concentrations were carried out in Gdynia. For intercalibration, a device was used that operates based on non-reference methodologies and without proven equivalence to the reference methodology (SEZO AM, WIRAN), and an EDM 180 analyzer (GRIMM) with certificates and approvals (US-EPA, UK-MCERTS, CN-CMA) was used. The aim of this research is to determine whether the SEZO AM device could be used in port areas for continuous PM2.5 and PM10 concentrations measurements. Two campaigns of two months allowed us to see a good agreement of the results achieved with both methods. The concordance of the results obtained from the SEZO AM and the EDM 180 methods amounted to between 78% and 94% for the PM2.5 and between 70% and 75% for the PM10. The comparison of two SEZO AM devices to a higher-class TSI OPS3330 reference in a measurement dust chamber showed a fit between 79% and 86% for the PM2.5 and between 81% and 86% for the PM10. This indicates the possibility of using this analyzer to measure the concentrations of PM2.5 and PM10 in the port atmosphere in which they were carried out. The preliminary analysis of meteorological parameters shows that the main potential impact on the concentration of the analyzed dust fractions measured by the SEZO AM method was relative humidity. The determination of the correction factor for the PM2.5 and PM10 concentrations and adding an inlet external cover contributed to a two-fold reduction in the analysis error and good concordance of the results, at a level of 93% for PM2.5 and 91% for PM10, without discarding any data.