The Use of Skeletonization for the Shape Classification of Carbon-Black Aggregates

Abstract

Abstract A specialized image analysis erosion technique, termed skeletonization, has been used for the first quantitative and direct measurement of branching in carbon-black aggregates. Twenty different carbon-black grades were analyzed using transmission-electron-microscopy/automated-image analysis (TEM/AIA). The skeletonization data were used in a discrimination analysis program for detailed shape classification of carbon-black aggregates into four different shape categories that included spheroidal (Type 1), ellipsoidal (Type 2), linear (Type 3) and branched (Type 4). These data were used to examine differences in the aggregate shape distributions between and within grades. Skeletonization and conventional TEM/AIA analyses were also conducted to examine aggregate breakdown as a result of high-shear mixing in rubber (SBR) and cellulose acetate butyrate (CAB) paint chip compounds. It was found that the number of aggregate branches decreased by as much as 50% in rubber and 70% in CAB compounds, and the distributions became narrower. Aggregate breakdown increases in the direction of the larger particle size carbon blacks which contain more linear (Type 3) aggregates. In rubber, an N650 (131 DBPA) and N330 (102 DBPA) carbon blacks were found to be similar in overall aggregate shape properties. Therefore, the significantly higher vulcanizate modulus for N650 appears to be related to a higher level of carbon-black—polymer interaction, as opposed to high amounts of polymer occluded and immobilized within the aggregate structure.