Abstract
The EMF of the cell glass electrode (Na)¦NaCl¦AgCl,Ag in water-tetrahydrofuran (THF) mixtures containing 0, 2.5, 7.5, 10, 15, 20, 25, 30 mol% THF has been measured within the temperature range 293.15–308.15 K. Standard EMF and thermodynamic functions of transfer of NaCl (Δ GXXX t, - TΔ S tXXX,Δ H tXXX) from water to water-THF mixtures were also determined. The values obtained have been compared with the corresponding values obtained by other authors. The possibilities of using cation-selective glass electrodes for thermodynamic studies on electrolyte solutions in systems containing aprotic solvents-water mixtures are evaluated including a critical review of the opinions of other authors.
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