Abstract
The probabilities for N2O5 loss onto sulfuric acid aerosol (60–80 wt % H2SO4, 0.1–0.2 um radius, 230–300K) were measured using a laminar flow reactor coupled to a sulfuric acid aerosol source and a chemical ionization mass spectrometer. The aerosol morphology was extracted from measurements of the aerosol extinction of ultraviolet light (200–370nm) by using Mie theory. The reaction probabilities, γ, are large (0.06–0.12) and are comparable to probabilities measured previously under similar conditions on bulk sulfuric acid surfaces and small aerosol. These measurements confirm that the overall reaction of N2O5 with H2O in/on 60–80% sulfuric acid is fast and the uptake is due to loss very close to the liquid surface.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.