The understanding of solid electrolyte interface (SEI) formation and mechanism as the effect of flouro‐o‐phenylenedimaleimaide (F‐MI) additive on lithium‐ion battery

Abstract

Solid electrolyte interface (SEI) is a critical factor that influences battery performance. SEI layer is formed by the decomposition of organic and inorganic compounds after the first cycle. This study investigates SEI formation as a product of electrolyte decomposition by the presence of flouro‐o‐phenylenedimaleimaide (F‐MI) additive. The presence of fluorine on the maleimide‐based additive can increase storage capacity and reversible discharge capacity due to high electronegativity and high electron‐withdrawing group. The electrolyte containing 0.1 wt% of F‐MI‐based additive can trigger the formation of SEI, which could suppress the decomposition of remaining electrolyte. The reduction potential was 2.35 to 2.21 V vs Li/Li+ as examined by cyclic voltammetry (CV). The mesocarbon microbeads (MCMB) cell with F‐MI additive showed the lowest SEI resistance (Rsei) at 5898 Ω as evaluated by the electrochemical impedance spectroscopy (EIS). The morphology and element analysis on the negative electrode after the first charge‐discharge cycle were examined by scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), and X‐ray photoelectron spectroscopy (XPS). XPS result showed that MCMB cell with F‐MI additive provides a higher intensity of organic compounds (RCH2OCO2Li) and thinner SEI than MCMB cell without an additive that provides a higher intensity of inorganic compound (Li2CO3 and Li2O), which leads to the performance decay. It is concluded that attaching the fluorine functional group on the maleimide‐based additive forms the ideal SEI formation for lithium‐ion battery.