The Uncertainty Evaluation of Determining the Trace H2S in SF6/N2 Insulating Gas Mixture by Cavity Ring-Down Spectroscopy

Abstract

Abstract H2S is one of the most important characteristic components of sulfur hexafluoride gas insulated electrical equipment. The detection of trace H2S is of great significance for early fault diagnosis of such equipment. Based on the 1578 nm wavelength distributed feedback diode laser (DFB-DL), cavity ring-down spectroscopy (CRDS) can effectively measure the concentration of trace H2S in SF6/N2 gas mixtures. Starting from the principle of methodology, this article establishes a mathematical model for evaluating the measurement uncertainty of CRDS and analyzes its sources of uncertainty: gas constant R1 , temperature T, Avogadro constant NA , gas pressure p in the optical cavity, volume V of the optical cavity, speed c of light, the absorption cross-section parameter σ(ν) of H2S molecules in the laser frequency ν, the ring-down time τ with absorption sample H2S and the ring-down time τ0 without absorption sample. After evaluating the uncertainty components, it was found that the main component was σ(ν) and the secondary components were τ and τ0. The H2S content in the 80% SF6-20% N2 mixed gas measured is (7.64 ± 0.12) × 10−6 mol/mol.