Abstract
The true potential energy curves for the bands of E 2 Σ +- X 2 Σ + system of the astrophysically important CN molecule have been calculated by RKRV and authors new methods and the agreement between the methods is found to be excellent. The ground state dissociation energy for the CN molecule calculated from the three-parameter Lippincott function is found to be in excellent agreement with the heat of formation value. The r-centroids and Franck-Condon factors for the bands of this system are also calculated and presented.
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