Abstract
A new tris(pyrazolyl)hydroborato ligand with anthryl susbtituents in the 3-position, tris[3-(9-anthryl)pyrazol-1-yl]hydroborate, [Tp Ant], has been synthesized by the reaction of KBH 4 with 3-(9-anthryl)pyrazole and characterized as the thallium derivative, Tl[Tp Ant]. The thallium reagent was used to prepare the cobalt and molybdenum derivatives, [Tp Ant]CoNCS and [Tp Ant]Mo(CO) 2( η 3-CH 2C(Me)CH 2). The molecular structure of [Tp Ant]CoNCS, contaminated with ca6% Tl[Tp Ant], has been determined by X-ray diffraction, thereby providing an example of compositional disorder between a vacancy and a chain of three atoms.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
