Abstract
The prosphorescence spectrum and zero-field transitions are reported for the triplet state of the quinoxalinium cation QH * (singly protonated 1,4-diazanaphthalene) as a guest in quinolinium perchlorate single crystals at 1.2 K. The kinetics of populating and decay of the triplet for QH * in two different sites have been determined by means of the MIDP method. The results do not give support to the idea that the QH * ion is non-planar in its metastable triplet state.
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