Abstract
Good linear correlations exist both between the bond dissociation energy of an Si-H bond and the corresponding SiH stretching frequency and between the 29 Si hyperfine splitting of a silicon-centered radical and J( 29 Si-H) for the corresponding silane, when the successive substitution at the Si-H function takes place inside a family, i.e., (Me 3 Si) 3-n Si(H)Me n , n=0-3. Explanations for these phenomena are advanced. Such structural correlations allow the characterization of (Me 3 Si) 2 Si(H)Me a radical-based reducing agent with low hydrogen-donating abilities
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
