The tribocorrosion behavior of the (AlCoCrFeNi)x/(WC–10Co)1-x composite coatings produced via high velocity oxy-fuel thermal spraying

Abstract

The (AlCoCrFeNi)x/(WC–10Co)1-x, (x = 100 wt%(HW1), 75 wt%(HW2), 50 wt% (HW3)) composite coatings are fabricated on 3Cr13 martensite stainless steel using high velocity oxy-fuel (HVOF) spraying technology, and the tribocorrosion experiment is carried out in artificial seawater. The tribocorrosion mechanism of the coatings and counterbody are analyzed. Particularly, the synergistic effect of corrosion and wear is explored using the ASTMG119. The introduction of WC-10Co improve the microhardness of the composite coatings, but decrease their corrosion resistance, which are due to the galvanic corrosion of the WC-10Co and HEA. Notably, the results of synergistic effect show that the corrosion of the HW1 coating has an inhibitory effect on wear. The volume loss of tribocorrosion increase with the introduction of WC-10Co, with the HW3 coating experiencing a volume loss of only 46 % compared to that of 3Cr13. The HW1 coating mainly suffers from abrasive wear, surface fatigue wear and adhesive wear. The main wear mechanism of the HW2 and HW3 coatings are abrasive wear, while the fatigue wear is enhanced with the participation of WC-10Co. And the counterbody of the three coatings mainly suffers abrasive wear.